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- W2034150008 abstract "C132-Alkylations of a 9:1 epimeric mixture of methyl pheophorbide a/a′, derived from naturally occurring chlorophyll a, were examined by using primary, secondary, and tertiary alkyl iodides. The sterically undemanding C132-alkylation of the methyl pheophorbide epimers successfully afforded their major (132R)- and minor (132S)-adducts, while the isopropylation primarily gave the (132S)-product and no desired adducts were obtained for tert-butyl and neopentyl substituents. The C132-alkylated epimers were separated by reverse phase-HPLC techniques and their stereochemistry was characterized by 1D/2D NMR spectroscopy." @default.
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- W2034150008 date "1980-03-01" @default.
- W2034150008 modified "2023-09-25" @default.
- W2034150008 title "A photoelectrochemical cell based on chlorophyll" @default.
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- W2034150008 doi "https://doi.org/10.1016/0040-6090(80)90397-1" @default.
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