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- W2034150685 abstract "Facial- and meridional-isomers of tris[benzyl(2-methylimidazol-4-ylmethylidene)amine]iron(II) chloride hexafluorophosphate with the formulas of fac-[Fe(HLMe-Benz)3]Cl·PF6·EtOH·H2O (1) and mer-[Fe(HLMe-Benz)3]Cl·PF6·1.5H2O (2) were selectively crystallized in ethanol and methanol, respectively. All three imidazole groups in both the fac- and mer-[Fe(HLMe-Benz)3]2+ cations are hydrogen-bonded to neighboring Cl− ions and give the assembly structures. The compounds differ, however, in that 1 has a discrete cubane-like tetranuclear cluster, while 2 forms a two-dimensional (2D) network structure. The magnetic susceptibilities data revealed that 1 and 2 are spin crossover complexes." @default.
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- W2034150685 date "2011-01-05" @default.
- W2034150685 modified "2023-09-28" @default.
- W2034150685 title "Assembly Structures and Spin Crossover Properties of Facial and Meridional Isomers of Tris[benzyl(2-methylimidazol-4-ylmethylidene)amine]iron(II) Chloride Hexafluorophosphate" @default.
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- W2034150685 doi "https://doi.org/10.1246/cl.2011.72" @default.
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