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• W2034153168 abstract "Dihalocarbene addition to allenic phosphine oxides occurs mainly at the allylic double bond. Treatment of dibromocarbene adducts with BuLi leads to cumulated trienephosphine oxides. In some cases, the intermediate alkylidenecyclopropylidene (or its precursor) is exceptionally stabilized, and this carbene (or carbenoid) is trapped by the corresponding cumulated trienephosphine oxide in a bimolecular process. The resultant spiropentane is formed in a regio- and stereoselective manner." @default.
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• W2034153168 date "1997-12-01" @default.
• W2034153168 modified "2023-09-25" @default.
• W2034153168 title "Cumulated Trienephosphine Oxides. Bimolecular Trapping of an Alkylidenecyclopropylidene" @default.
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• W2034153168 doi "https://doi.org/10.1021/jo970771u" @default.
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