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- W2034154334 abstract "α-Alkyl substituted fluorenylidene allene oxides were generated photochemically from appropriately substituted fluorenol derivatives in 2,2,2-trifluoroethanol (TFE) in order to assess the affect of steric bulk on the absolute reactivity of the allene oxides. The absolute reactivities of the allene oxides were measured using nanosecond laser flash photolysis, and were found to change little in TFE upon going from α-methyl to α-butyl to α-t-butyl. However, all three α-alkyl substituted allene oxides were considerably more reactive than the α-hydrogen derivative, indicating that steric bulk did not result in a decrease in reactivity as is typically found in other allene oxides. The contrary reactivity of the fluorenylidene allene oxides is explained by examining in detail the reactions of these allene oxides, determined from product studies." @default.
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- W2034154334 date "2009-01-01" @default.
- W2034154334 modified "2023-09-27" @default.
- W2034154334 title "Effect of steric bulk on the absolute reactivity of allene oxides" @default.
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- W2034154334 doi "https://doi.org/10.1039/b910887d" @default.
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