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- W2034155904 startingPage "1031" @default.
- W2034155904 abstract "The β-elimination reaction of methyl 3-chloroalaninate has been investigated in the absence and presence of pyridoxal methochloride (2) or pyridoxal (3). Apparently, compound 2 was about twice as effective as 3 in the catalytic reaction that proceeds via a Schiff base of substrate and 2 or 3. The pH-rate profiles for the catalytic reaction with 2 and 3 were analyzed in terms of ionization of the various Schiff base species present in solution. It was found that the reactivity of the Schiff base decreases as the ionization of the molecule progresses. The reaction mechanism and its relevance to the catalysis of pyridoxal phosphate–dependent enzymes are discussed." @default.
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- W2034155904 date "1984-04-01" @default.
- W2034155904 modified "2023-09-26" @default.
- W2034155904 title "Pyridoxal Methochloride Catalysis of the β-Elimination Reaction of Methyl 3-Chloroalaninate in Water" @default.
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- W2034155904 doi "https://doi.org/10.1246/bcsj.57.1031" @default.
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