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- W2034160255 abstract "Raman-scattering spectra of α-As4S4 and β-As4S4 have been determined at 300 and 10 K. Although similar in overall aspect, the spectral signatures of the two polymorphs are clearly distinct. We have made a careful comparison of these first-order crystal line spectra to the sharp features reported in the Raman spectra of freshly-deposited films of amorphous As2S3. Prior proposals for the presence of As4S4 molecules in the unannealed films are supported by these comparisons, but recent contentions that actual microcrystals of β-As4S4 are present in the as-deposited material are clearly contradicted by the absence of any of the lattice-phonon lines which are prominent in the crystals at frequencies below 70 cm-1." @default.
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- W2034160255 date "1979-05-01" @default.
- W2034160255 modified "2023-09-26" @default.
- W2034160255 title "Raman spectra of As4S4 polymorphs: Structural implications for amorphous As2S3 films" @default.
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- W2034160255 doi "https://doi.org/10.1016/0038-1098(79)90651-3" @default.
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