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- W2034163168 abstract "Orthochloranil-mediated oxidation of galloyl monoethers furnishes the derived orthoquinones in excellent yield. These reactive electrophiles participate in a variety of nucleophilic addition reactions with heteroatomic and carbanionic partners. In addition, Lewis acid-mediated dimerization of the orthoquinones provides an efficient route to dehydrodigalloyl-type diaryl ether units characteristic of several ellagitannin natural products. The implications for ellagitannin biosynthesis and gallotannin-protein covalent attachment are discussed." @default.
- W2034163168 created "2016-06-24" @default.
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- W2034163168 date "1996-01-01" @default.
- W2034163168 modified "2023-10-03" @default.
- W2034163168 title "Galloyl-Derived Orthoquinones as Reactive Partners in Nucleophilic Additions and Diels−Alder Dimerizations: A Novel Route to the Dehydrodigalloyl Linker Unit of Agrimoniin-Type Ellagitannins" @default.
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- W2034163168 doi "https://doi.org/10.1021/jo961043u" @default.
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