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• W2034165220 endingPage "264" @default.
• W2034165220 startingPage "257" @default.
• W2034165220 abstract "The incoherent inelastic neutron scattering (INS) spectra of Mn0.84PS3[Co(C5H5)2] 0.32 and Mn0.86 PS3[Cr(C6H6)2]0.28 compounds at 10 K have been investigated within the frequency ranges 0–80 cm−1 (E0 = 12.5 meV) and 0–360 cm−1 (E0 = 50 meV). Also, infrared and Raman spectra (0–400 cm−1 of Cr(C6H6)2I at various temperatures have been obtained for the first time. From a comparison of far infrared, low frequency Raman and INS results, we propose an assignment for the internal torsion and for the librational motions in the intercalated organometallic cations. An estimate of the potential barrier height against the torsion and the R′z whole-body rotation is derived; these values are compared with those calculated for the corresponding iodide salts. We conclude that a significant decrease of the intermolecular forces acting on the rings is taking place within the interlamellar space." @default.
• W2034165220 created "2016-06-24" @default.
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• W2034165220 date "1982-10-01" @default.
• W2034165220 modified "2023-09-25" @default.
• W2034165220 title "Inelastic neutron scattering study of low frequency motions in [Co(C5H5)2+] and [Cr(C6 H62+] intercalated in the MnPS3 layered compound" @default.
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• W2034165220 doi "https://doi.org/10.1016/0301-0104(82)87025-0" @default.
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