Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034166291> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2034166291 endingPage "266" @default.
- W2034166291 startingPage "253" @default.
- W2034166291 abstract "A method was developed and optimised for the emulsification of a conventional short oil alkyd resin which was solid at room temperature. The method was based on the emulsion inversion point (EIP) method whereby hot water (90°C) was added to molten alkyd resin (90°C) containing the emulsifier. Under slow mixing and addition of water, a point was reached where the emulsion instantaneously phase inverted from a water in oil emulsion (W/O) to an oil in water emulsion (O/W). Using optimum conditions, emulsions with droplet of diameters less than 0.8 μm were obtained. The drying and film formation of long oil alkyd emulsions were investigated with emphasis on loss of dry upon storage. The main reason for loss of dry was adsorption of the cobalt (drier) on pigment surfaces as a precipitated hydroxide. Titanium dioxides with alumina surface treatment and organic pigments were most detrimental to drying. Acrylate- and phosphate-based dispersants also deactivated cobalt presumably due to complexation and precipitation of cobalt. Emulsions prepared with an emulsifiable cobalt drier containing 2,2′-bipyridyl (complexing agent for cobalt) showed the best resistance to loss of dry. Films formed from the emulsions showed that surfactant migrated to the film surface which when washed with water leaves holes or pits in film. The pits were arranged in a hexagonal pattern, characteristic of Bénard cells which form due to interfacial tension gradients generated in the film during evaporation of water." @default.
- W2034166291 created "2016-06-24" @default.
- W2034166291 creator A5045185529 @default.
- W2034166291 creator A5081406965 @default.
- W2034166291 date "2000-12-01" @default.
- W2034166291 modified "2023-10-14" @default.
- W2034166291 title "Emulsification, drying and film formation of alkyd emulsions" @default.
- W2034166291 cites W1974586838 @default.
- W2034166291 cites W1989129141 @default.
- W2034166291 cites W2004200788 @default.
- W2034166291 cites W2018553725 @default.
- W2034166291 cites W2019557753 @default.
- W2034166291 cites W2033250652 @default.
- W2034166291 cites W2052631758 @default.
- W2034166291 cites W2075272544 @default.
- W2034166291 cites W2076848257 @default.
- W2034166291 doi "https://doi.org/10.1016/s0300-9440(00)00120-x" @default.
- W2034166291 hasPublicationYear "2000" @default.
- W2034166291 type Work @default.
- W2034166291 sameAs 2034166291 @default.
- W2034166291 citedByCount "33" @default.
- W2034166291 countsByYear W20341662912012 @default.
- W2034166291 countsByYear W20341662912014 @default.
- W2034166291 countsByYear W20341662912015 @default.
- W2034166291 countsByYear W20341662912017 @default.
- W2034166291 countsByYear W20341662912018 @default.
- W2034166291 countsByYear W20341662912019 @default.
- W2034166291 crossrefType "journal-article" @default.
- W2034166291 hasAuthorship W2034166291A5045185529 @default.
- W2034166291 hasAuthorship W2034166291A5081406965 @default.
- W2034166291 hasConcept C120665830 @default.
- W2034166291 hasConcept C121332964 @default.
- W2034166291 hasConcept C127413603 @default.
- W2034166291 hasConcept C145889102 @default.
- W2034166291 hasConcept C159985019 @default.
- W2034166291 hasConcept C162585328 @default.
- W2034166291 hasConcept C171431902 @default.
- W2034166291 hasConcept C177562468 @default.
- W2034166291 hasConcept C185592680 @default.
- W2034166291 hasConcept C191897082 @default.
- W2034166291 hasConcept C192562407 @default.
- W2034166291 hasConcept C2778123984 @default.
- W2034166291 hasConcept C2781448156 @default.
- W2034166291 hasConcept C41625074 @default.
- W2034166291 hasConcept C42360764 @default.
- W2034166291 hasConcept C515602321 @default.
- W2034166291 hasConcept C55493867 @default.
- W2034166291 hasConcept C58226133 @default.
- W2034166291 hasConcept C61441594 @default.
- W2034166291 hasConcept C62520636 @default.
- W2034166291 hasConcept C8892853 @default.
- W2034166291 hasConcept C97355855 @default.
- W2034166291 hasConceptScore W2034166291C120665830 @default.
- W2034166291 hasConceptScore W2034166291C121332964 @default.
- W2034166291 hasConceptScore W2034166291C127413603 @default.
- W2034166291 hasConceptScore W2034166291C145889102 @default.
- W2034166291 hasConceptScore W2034166291C159985019 @default.
- W2034166291 hasConceptScore W2034166291C162585328 @default.
- W2034166291 hasConceptScore W2034166291C171431902 @default.
- W2034166291 hasConceptScore W2034166291C177562468 @default.
- W2034166291 hasConceptScore W2034166291C185592680 @default.
- W2034166291 hasConceptScore W2034166291C191897082 @default.
- W2034166291 hasConceptScore W2034166291C192562407 @default.
- W2034166291 hasConceptScore W2034166291C2778123984 @default.
- W2034166291 hasConceptScore W2034166291C2781448156 @default.
- W2034166291 hasConceptScore W2034166291C41625074 @default.
- W2034166291 hasConceptScore W2034166291C42360764 @default.
- W2034166291 hasConceptScore W2034166291C515602321 @default.
- W2034166291 hasConceptScore W2034166291C55493867 @default.
- W2034166291 hasConceptScore W2034166291C58226133 @default.
- W2034166291 hasConceptScore W2034166291C61441594 @default.
- W2034166291 hasConceptScore W2034166291C62520636 @default.
- W2034166291 hasConceptScore W2034166291C8892853 @default.
- W2034166291 hasConceptScore W2034166291C97355855 @default.
- W2034166291 hasIssue "1-4" @default.
- W2034166291 hasLocation W20341662911 @default.
- W2034166291 hasOpenAccess W2034166291 @default.
- W2034166291 hasPrimaryLocation W20341662911 @default.
- W2034166291 hasRelatedWork W2031433750 @default.
- W2034166291 hasRelatedWork W2291545532 @default.
- W2034166291 hasRelatedWork W2374521807 @default.
- W2034166291 hasRelatedWork W2380276890 @default.
- W2034166291 hasRelatedWork W2388502414 @default.
- W2034166291 hasRelatedWork W2389974177 @default.
- W2034166291 hasRelatedWork W3047528133 @default.
- W2034166291 hasRelatedWork W4243356832 @default.
- W2034166291 hasRelatedWork W4384133890 @default.
- W2034166291 hasRelatedWork W2522426867 @default.
- W2034166291 hasVolume "40" @default.
- W2034166291 isParatext "false" @default.
- W2034166291 isRetracted "false" @default.
- W2034166291 magId "2034166291" @default.
- W2034166291 workType "article" @default.