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- W2034170039 abstract "Densities of solutions of CaCl2 in the mixtures of water and methanol have been measured at 25°C and the apparent molar volume of solute, φv, was calculated. Experimental concentration dependence of φ v was compared with the coefficient Sv derived from the Debye-Hückel theory. The relation between φv — Svc1/2 and c is linear but the slopes changed from horizontal to gradually negative with increase of the methanol content in the solvents, showing that in addition to interionic interactions expressed by the D-H theory, some types of solute-solute interactions are working in the solutions. V 2˚ of CaCl2 decreased remarkably in the methanol-rich regions. This is ascribable to the strong electrostricion effect of Ca2+ ion in solutions." @default.
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- W2034170039 date "1985-03-01" @default.
- W2034170039 modified "2023-09-26" @default.
- W2034170039 title "PARTIAL MOLAR VOLUMES OF CaCl2 IN WATER-METHANOL MIXTURES AND THE APPLICABILITY OF THE DEBYE-HÜCKEL THEORY" @default.
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