FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034173175> ?p ?o ?g. }

• W2034173175 endingPage "152" @default.
• W2034173175 startingPage "144" @default.
• W2034173175 abstract "The reaction of [Rh{κ2-O2S(O)CF3}(PiPr3)2] (1) with ethynylferrocene in the presence of KF affords the substituted vinylidene complex trans-[RhF{CCH(C5H4)Fe(C5H5)}(PiPr3)2] (2) which upon treatment with the butadiyne derivative Ph3SnCCCCSnPh3 produces the chain-like compound trans-[(μ-CCCC){Rh(CCH(C5H4)Fe(C5H5))(PiPr3)2}2] (7). The triflato complex 1 reacts with 1,4-C6H4(CCH)2 to give the dinuclear compound trans-[{μ-1,4-C6H4(CHC)2}{Rh(η1-OS(O)2CF3)(PiPr3)2}2] (3) which in the presence of KF undergoes a ligand exchange to give the corresponding difluoro derivative 4. From 4 and RCCSnPh3 (R=CH3, C6H5) the complexes 5 and 6, in which a C6H4 unit bridges two alkynyl(vinylidene)rhodium(I) fragments, are obtained. Both 6 and 7 react with CO by migratory insertion of the vinylidene units into the alkynyl-metal bonds to afford the dinuclear complexes 8 and 9, in which an unusual C8 or C4(C6H4)C4 chain bridges the two rhodium centers. The reactions of [RhCl(PiPr3)2]2 (10) with the functionalized diynes 1,1′,4,4′-C6H4(OH)2(CCH)2 and 1,4-C6H4[C(Ph)(OH)CCH]2 lead, via the corresponding diyne-metal species 11 and 12 as intermediates, to the formation of the bis(vinylidene) complexes 13 and 14, the latter of which reacts with acidic Al2O3 by elimination of water to give the novel phenylene-bridged bis(allenylidenerhodium) compound [{μ-1,4-C6H4(CPhCC)2}{RhCl(PiPr3)2}2] (15) in 80% yield." @default.
• W2034173175 created "2016-06-24" @default.
• W2034173175 creator A5083976317 @default.
• W2034173175 creator A5086562220 @default.
• W2034173175 creator A5090724147 @default.
• W2034173175 date "2003-11-01" @default.
• W2034173175 modified "2023-09-25" @default.
• W2034173175 title "Synthesis and reactivity of dinuclear rhodium complexes with RhCCHR and RhCCCRR′ units as building blocks" @default.
• W2034173175 cites W1512067969 @default.
• W2034173175 cites W1810985463 @default.
• W2034173175 cites W1964067197 @default.
• W2034173175 cites W1965218344 @default.
• W2034173175 cites W1969694854 @default.
• W2034173175 cites W1984218077 @default.
• W2034173175 cites W2010851420 @default.
• W2034173175 cites W2017053652 @default.
• W2034173175 cites W2017830289 @default.
• W2034173175 cites W2021725183 @default.
• W2034173175 cites W2023099374 @default.
• W2034173175 cites W2031726130 @default.
• W2034173175 cites W2032763701 @default.
• W2034173175 cites W2040188040 @default.
• W2034173175 cites W2043276791 @default.
• W2034173175 cites W2043641078 @default.
• W2034173175 cites W2070064528 @default.
• W2034173175 cites W2072679172 @default.
• W2034173175 cites W2080297440 @default.
• W2034173175 cites W2083455246 @default.
• W2034173175 cites W2088563252 @default.
• W2034173175 cites W2090075468 @default.
• W2034173175 cites W2094225618 @default.
• W2034173175 cites W2107306140 @default.
• W2034173175 doi "https://doi.org/10.1016/s0022-328x(03)00521-7" @default.
• W2034173175 hasPublicationYear "2003" @default.
• W2034173175 type Work @default.
• W2034173175 sameAs 2034173175 @default.
• W2034173175 citedByCount "26" @default.
• W2034173175 countsByYear W20341731752012 @default.
• W2034173175 countsByYear W20341731752018 @default.
• W2034173175 countsByYear W20341731752022 @default.
• W2034173175 crossrefType "journal-article" @default.
• W2034173175 hasAuthorship W2034173175A5083976317 @default.
• W2034173175 hasAuthorship W2034173175A5086562220 @default.
• W2034173175 hasAuthorship W2034173175A5090724147 @default.
• W2034173175 hasConcept C106159729 @default.
• W2034173175 hasConcept C111771559 @default.
• W2034173175 hasConcept C116569031 @default.
• W2034173175 hasConcept C137955730 @default.
• W2034173175 hasConcept C142724271 @default.
• W2034173175 hasConcept C155647269 @default.
• W2034173175 hasConcept C161790260 @default.
• W2034173175 hasConcept C162324750 @default.
• W2034173175 hasConcept C170493617 @default.
• W2034173175 hasConcept C178790620 @default.
• W2034173175 hasConcept C185592680 @default.
• W2034173175 hasConcept C204787440 @default.
• W2034173175 hasConcept C2776910235 @default.
• W2034173175 hasConcept C521398313 @default.
• W2034173175 hasConcept C544153396 @default.
• W2034173175 hasConcept C55493867 @default.
• W2034173175 hasConcept C71240020 @default.
• W2034173175 hasConcept C71924100 @default.
• W2034173175 hasConceptScore W2034173175C106159729 @default.
• W2034173175 hasConceptScore W2034173175C111771559 @default.
• W2034173175 hasConceptScore W2034173175C116569031 @default.
• W2034173175 hasConceptScore W2034173175C137955730 @default.
• W2034173175 hasConceptScore W2034173175C142724271 @default.
• W2034173175 hasConceptScore W2034173175C155647269 @default.
• W2034173175 hasConceptScore W2034173175C161790260 @default.
• W2034173175 hasConceptScore W2034173175C162324750 @default.
• W2034173175 hasConceptScore W2034173175C170493617 @default.
• W2034173175 hasConceptScore W2034173175C178790620 @default.
• W2034173175 hasConceptScore W2034173175C185592680 @default.
• W2034173175 hasConceptScore W2034173175C204787440 @default.
• W2034173175 hasConceptScore W2034173175C2776910235 @default.
• W2034173175 hasConceptScore W2034173175C521398313 @default.
• W2034173175 hasConceptScore W2034173175C544153396 @default.
• W2034173175 hasConceptScore W2034173175C55493867 @default.
• W2034173175 hasConceptScore W2034173175C71240020 @default.
• W2034173175 hasConceptScore W2034173175C71924100 @default.
• W2034173175 hasIssue "1-2" @default.
• W2034173175 hasLocation W20341731751 @default.
• W2034173175 hasOpenAccess W2034173175 @default.
• W2034173175 hasPrimaryLocation W20341731751 @default.
• W2034173175 hasRelatedWork W1482811895 @default.
• W2034173175 hasRelatedWork W1972310089 @default.
• W2034173175 hasRelatedWork W1995261565 @default.
• W2034173175 hasRelatedWork W2013986867 @default.
• W2034173175 hasRelatedWork W2067123649 @default.
• W2034173175 hasRelatedWork W2072072954 @default.
• W2034173175 hasRelatedWork W2078250055 @default.
• W2034173175 hasRelatedWork W2323388872 @default.
• W2034173175 hasRelatedWork W2515935008 @default.
• W2034173175 hasRelatedWork W4237330838 @default.
• W2034173175 hasVolume "684" @default.
• W2034173175 isParatext "false" @default.
• W2034173175 isRetracted "false" @default.
• W2034173175 magId "2034173175" @default.

• next