FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034175413> ?p ?o ?g. }

• W2034175413 endingPage "157" @default.
• W2034175413 startingPage "149" @default.
• W2034175413 abstract "The simultaneous synthesis of butyric acid methyl ester, the shortest component of the FAME (fatty acid methyl esters) family, and glycerol triacetate (TAG) from glycerol tributyrate (tributyrin) and methyl acetate was studied as a function of several reaction parameters, such as type of catalyst, temperature and products distribution. The reaction is an interesterification, a multistep consecutive ester interchange catalyzed by either acid or base catalyst. Under optimized conditions, a complete tributyrin conversion and an almost quantitative butyric acid methyl ester accumulation were achieved. The other reaction product, TAG, formed by the complete acetylation of the glycerol moiety, reached almost 70% yield, whereas the mono- and di-acetylated intermediates accumulated in the order of 5–8% and 24–27%, respectively. Similar final conversions and products yields were obtained with either acid or base homogeneous catalysts, suggesting that the final products mixture did not depend on the type of catalysis but might be limited by equilibrium conditions. In spite of similar final yields, base catalysis needed shorter reaction times (minutes instead of hours) and lower temperature (60 °C instead of 130 °C) with respect to the best acid catalyst. On the other hand, unlike heterogeneous basic catalysts, which showed low activity, a heterogeneous acid catalyst almost as active as the homogenous counterpart was found." @default.
• W2034175413 created "2016-06-24" @default.
• W2034175413 creator A5002626184 @default.
• W2034175413 creator A5016124155 @default.
• W2034175413 creator A5017274854 @default.
• W2034175413 creator A5017437514 @default.
• W2034175413 creator A5036381873 @default.
• W2034175413 date "2011-02-01" @default.
• W2034175413 modified "2023-10-01" @default.
• W2034175413 title "Co-production of butyrate methyl ester and triacetylglycerol from tributyrin and methyl acetate" @default.
• W2034175413 cites W1583236421 @default.
• W2034175413 cites W1966682256 @default.
• W2034175413 cites W1970252081 @default.
• W2034175413 cites W1973735548 @default.
• W2034175413 cites W1975944613 @default.
• W2034175413 cites W1978287157 @default.
• W2034175413 cites W1981050956 @default.
• W2034175413 cites W1981848964 @default.
• W2034175413 cites W2002123062 @default.
• W2034175413 cites W2010686574 @default.
• W2034175413 cites W2010787244 @default.
• W2034175413 cites W2027380358 @default.
• W2034175413 cites W2028099824 @default.
• W2034175413 cites W2033556971 @default.
• W2034175413 cites W2041923960 @default.
• W2034175413 cites W2048770920 @default.
• W2034175413 cites W2054781839 @default.
• W2034175413 cites W2066828315 @default.
• W2034175413 cites W2073320336 @default.
• W2034175413 cites W2078323144 @default.
• W2034175413 cites W2088609625 @default.
• W2034175413 cites W2091179438 @default.
• W2034175413 cites W2092415556 @default.
• W2034175413 cites W2092994063 @default.
• W2034175413 cites W2095942007 @default.
• W2034175413 cites W2096530864 @default.
• W2034175413 cites W2111431564 @default.
• W2034175413 cites W2143765146 @default.
• W2034175413 cites W2156927600 @default.
• W2034175413 doi "https://doi.org/10.1016/j.apcata.2010.12.029" @default.
• W2034175413 hasPublicationYear "2011" @default.
• W2034175413 type Work @default.
• W2034175413 sameAs 2034175413 @default.
• W2034175413 citedByCount "12" @default.
• W2034175413 countsByYear W20341754132013 @default.
• W2034175413 countsByYear W20341754132014 @default.
• W2034175413 countsByYear W20341754132015 @default.
• W2034175413 countsByYear W20341754132017 @default.
• W2034175413 countsByYear W20341754132018 @default.
• W2034175413 countsByYear W20341754132019 @default.
• W2034175413 countsByYear W20341754132020 @default.
• W2034175413 countsByYear W20341754132023 @default.
• W2034175413 crossrefType "journal-article" @default.
• W2034175413 hasAuthorship W2034175413A5002626184 @default.
• W2034175413 hasAuthorship W2034175413A5016124155 @default.
• W2034175413 hasAuthorship W2034175413A5017274854 @default.
• W2034175413 hasAuthorship W2034175413A5017437514 @default.
• W2034175413 hasAuthorship W2034175413A5036381873 @default.
• W2034175413 hasBestOaLocation W20341754132 @default.
• W2034175413 hasConcept C120648863 @default.
• W2034175413 hasConcept C134121241 @default.
• W2034175413 hasConcept C134306372 @default.
• W2034175413 hasConcept C161790260 @default.
• W2034175413 hasConcept C178790620 @default.
• W2034175413 hasConcept C181199279 @default.
• W2034175413 hasConcept C185592680 @default.
• W2034175413 hasConcept C191897082 @default.
• W2034175413 hasConcept C192562407 @default.
• W2034175413 hasConcept C2775997716 @default.
• W2034175413 hasConcept C2776568683 @default.
• W2034175413 hasConcept C2776781215 @default.
• W2034175413 hasConcept C2778855143 @default.
• W2034175413 hasConcept C2779697368 @default.
• W2034175413 hasConcept C2779843069 @default.
• W2034175413 hasConcept C2780209386 @default.
• W2034175413 hasConcept C2780881558 @default.
• W2034175413 hasConcept C33923547 @default.
• W2034175413 hasConcept C42058472 @default.
• W2034175413 hasConcept C52896960 @default.
• W2034175413 hasConceptScore W2034175413C120648863 @default.
• W2034175413 hasConceptScore W2034175413C134121241 @default.
• W2034175413 hasConceptScore W2034175413C134306372 @default.
• W2034175413 hasConceptScore W2034175413C161790260 @default.
• W2034175413 hasConceptScore W2034175413C178790620 @default.
• W2034175413 hasConceptScore W2034175413C181199279 @default.
• W2034175413 hasConceptScore W2034175413C185592680 @default.
• W2034175413 hasConceptScore W2034175413C191897082 @default.
• W2034175413 hasConceptScore W2034175413C192562407 @default.
• W2034175413 hasConceptScore W2034175413C2775997716 @default.
• W2034175413 hasConceptScore W2034175413C2776568683 @default.
• W2034175413 hasConceptScore W2034175413C2776781215 @default.
• W2034175413 hasConceptScore W2034175413C2778855143 @default.
• W2034175413 hasConceptScore W2034175413C2779697368 @default.
• W2034175413 hasConceptScore W2034175413C2779843069 @default.
• W2034175413 hasConceptScore W2034175413C2780209386 @default.
• W2034175413 hasConceptScore W2034175413C2780881558 @default.
• W2034175413 hasConceptScore W2034175413C33923547 @default.
• W2034175413 hasConceptScore W2034175413C42058472 @default.

• next