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- W2034175955 abstract "By Swern oxidation of the hydroxamic acid 3 , prepared from the homochiral imidazolidin-2-one 1 , the transient C-nitroso derivative 4 is obtained, and its cycloaddition to either cyclohexadiene or cyclopentadiene proceeds with high diastereoselection, owing to the conformational stability of 4 . The stereochemical outcome of the reaction is determined from 1 H NMR data and further confirmed by the specific rotation value of 7 , obtained by cleavage of the major cycloadduct 5a . Graphic" @default.
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- W2034175955 date "1994-08-01" @default.
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- W2034175955 title "Diastereoselective hetero-diels-alder cycloaddition of a C-nitroso compound prepared starting from a homochiral imidazolidin-2-one" @default.
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- W2034175955 doi "https://doi.org/10.1016/0957-4166(94)80123-1" @default.
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