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- W2034182162 abstract "The assignment of the absolute configuration of hydroxy- and aminophosphonates by their double derivatization with commercially available naproxen is presented. The correlation between the spatial arrangement around the stereogenic carbon center and the signs of the ΔδRS allows determination of the absolute configuration of hydroxy- and aminophosphonates by simple comparison of the 1H and 31P NMR spectra of the (R)- and (S)-naproxen ester or amide derivatives. Extensive conformational analysis (theoretical calculations, low-temperature experiments) supported by the NMR studies of structurally diverse naproxen esters and amides of hydroxy- and aminophosphonates proved that a simplified model can be successfully used." @default.
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- W2034182162 date "2007-01-10" @default.
- W2034182162 modified "2023-10-12" @default.
- W2034182162 title "The Assignment of the Absolute Configuration of Diethyl Hydroxy- and Aminophosphonates by <sup>1</sup>H and <sup>31</sup>P NMR Using Naproxen as a Reliable Chiral Derivatizing Agent" @default.
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- W2034182162 doi "https://doi.org/10.1021/jo062097z" @default.
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