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- W2034182671 abstract "2,2-Dimethyl-3-phenyl-3-allylaziridine (Az) reacts with Cramer's complex [Rh(C2H4)2Cl2] to give [Rh(AZ)(C2H4)Cl]. This new complex is transformed by carbon monoxide into [Rh(Az)(CO)Cl], which can be also prepared starting from [Rh(CO2)Cl2]. The crystal and molecular structure of this carbonyl species has been fully solved by X-ray diffraction, providing the first example of a complex with bidentate aziridine. The ethylene complex reacts with one equivalent of triphenylphosphine to give [Rh(Az)(PPh3)Cl]. A second equivalent of phosphine does not create a monodentate aziridine, but displaces this ligand. Similar behaviour is observed with the carbonyl complex which gives free aziridine and trans-[Rh(CO)(PPh3)2Cl]." @default.
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- W2034182671 date "1992-10-01" @default.
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- W2034182671 title "Synthesis and characterization of rhodium complexes [Rh(Az)(L)Cl] (Az 2,2-dimethyl-3-phenyl-3-allylaziridine; L C2H4, CO, or" @default.
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- W2034182671 doi "https://doi.org/10.1016/0022-328x(92)88020-j" @default.
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