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- W203418508 abstract "A new fitting tool for analysis of multiple molecular absorption spectra utilizing a microwindow-based line-by-lineapproachhas been developed. Its capabilities include the choice of numerous different line shape models, from a simpleVoigt to more sophisticated models like a speed-dependent Galatry including line-mixing. A comfortable manual mode aswell as a fully automatic mode have been implemented including various quality assessment procedures like themonitoring of correlation coefficients or the supply of useful information e.g. needed for file cuts (single spectrumresiduals). As a first application the new tool is used to re-analyze water vapor absorption spectra in the 1250-1750 cm range. The measurements include pure water as well as water/air-mixture measurements and cover a wide range of column densities. The total air pressure and partial pressure ranges were 50-1000 mb and 0.001-5 mb, respectively.Whereas the original analysis was based on single spectrum fits applying the Voigt procedure, in the presentmultispectrum fit the speed-dependent Voigt lineshape was used. The advantages of a multispectral analyis approach aswell as the need for consideration of narrowing effects is illustrated by the presentation of differences in residuals as well as resulting line parameters for selected transitions. As indicated in opaque as well as non opaque lines could be fittedwith the speed-dependent Voigt while the pure Voigt yields to narrow opaque lines." @default.
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- W203418508 date "2013-08-01" @default.
- W203418508 modified "2023-09-27" @default.
- W203418508 title "Multispectrum fit of non-Voigt lineshape in the H2O v2 band" @default.
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