FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034187009> ?p ?o ?g. }

• W2034187009 endingPage "1989" @default.
• W2034187009 startingPage "1983" @default.
• W2034187009 abstract "A series of MFI supported bimetallic catalysts with high Co/Pd ratios and high metal loading was prepared by first subliming CoBr2 vapor onto H/MFI, followed by ion exchange of some Pd from an aqueous solution of Pd(NH3)4(NO3)2. They were tested for NO reduction with CH4 in the presence of 2% O2. Best performance was observed with Co/Pd = 14/1. In this catalyst Pd0 sites are assumed to activate methane. At higher Pd loading the catalytic selectivity is lower because large PdO particles are formed, which catalyze methane combustion. The reducibility of Co is significantly enhanced by small amounts of Pd. At 55 °C, the Pd and a comparable amount of Co are co-reduced. The particles consist of two phases, including a phase of almost pure Pd capable of forming Pd hydride. Metal reduction is complete at 550 °C. Many reduced particles are biphasic, with a Pd-rich kernel and Co-rich mantle. EXAFS reveals Pd–Co bonds at the interface. A substantial reorganization of the metal particles takes place at 800 °C, Pd-rich large alloy particles coexist with small particles of Co and Co-rich alloy. The alloy particles exhibit high and stable activity for NO reduction to N2 with CH4 at 300 °C, but lose this activity at high reaction temperature." @default.
• W2034187009 created "2016-06-24" @default.
• W2034187009 creator A5014620636 @default.
• W2034187009 creator A5023183757 @default.
• W2034187009 creator A5064332635 @default.
• W2034187009 creator A5078914466 @default.
• W2034187009 creator A5089404504 @default.
• W2034187009 creator A5091640807 @default.
• W2034187009 date "2002-04-05" @default.
• W2034187009 modified "2023-09-23" @default.
• W2034187009 title "Synergism of cobalt and palladium in MFI zeolite of relevance to NO reduction with methane" @default.
• W2034187009 cites W1964188721 @default.
• W2034187009 cites W1968046406 @default.
• W2034187009 cites W1974475155 @default.
• W2034187009 cites W1982104363 @default.
• W2034187009 cites W1986622067 @default.
• W2034187009 cites W1987202086 @default.
• W2034187009 cites W1990967700 @default.
• W2034187009 cites W1995710163 @default.
• W2034187009 cites W1999983216 @default.
• W2034187009 cites W2002221611 @default.
• W2034187009 cites W2002816822 @default.
• W2034187009 cites W2014271818 @default.
• W2034187009 cites W2020631260 @default.
• W2034187009 cites W2029075116 @default.
• W2034187009 cites W2034559748 @default.
• W2034187009 cites W2034630650 @default.
• W2034187009 cites W2039763361 @default.
• W2034187009 cites W2042927153 @default.
• W2034187009 cites W2046326334 @default.
• W2034187009 cites W2053496935 @default.
• W2034187009 cites W2056873767 @default.
• W2034187009 cites W2058068451 @default.
• W2034187009 cites W2059032275 @default.
• W2034187009 cites W2064259673 @default.
• W2034187009 cites W2074649621 @default.
• W2034187009 cites W2081269460 @default.
• W2034187009 cites W2081457294 @default.
• W2034187009 cites W2088512861 @default.
• W2034187009 cites W2112721197 @default.
• W2034187009 cites W2134372251 @default.
• W2034187009 cites W2161171078 @default.
• W2034187009 cites W2172068455 @default.
• W2034187009 cites W2752935765 @default.
• W2034187009 doi "https://doi.org/10.1039/b111200g" @default.
• W2034187009 hasPublicationYear "2002" @default.
• W2034187009 type Work @default.
• W2034187009 sameAs 2034187009 @default.
• W2034187009 citedByCount "16" @default.
• W2034187009 countsByYear W20341870092016 @default.
• W2034187009 countsByYear W20341870092017 @default.
• W2034187009 countsByYear W20341870092019 @default.
• W2034187009 countsByYear W20341870092022 @default.
• W2034187009 crossrefType "journal-article" @default.
• W2034187009 hasAuthorship W2034187009A5014620636 @default.
• W2034187009 hasAuthorship W2034187009A5023183757 @default.
• W2034187009 hasAuthorship W2034187009A5064332635 @default.
• W2034187009 hasAuthorship W2034187009A5078914466 @default.
• W2034187009 hasAuthorship W2034187009A5089404504 @default.
• W2034187009 hasAuthorship W2034187009A5091640807 @default.
• W2034187009 hasConcept C127413603 @default.
• W2034187009 hasConcept C161790260 @default.
• W2034187009 hasConcept C178790620 @default.
• W2034187009 hasConcept C179104552 @default.
• W2034187009 hasConcept C185592680 @default.
• W2034187009 hasConcept C192562407 @default.
• W2034187009 hasConcept C2777961443 @default.
• W2034187009 hasConcept C2778077586 @default.
• W2034187009 hasConcept C2780026712 @default.
• W2034187009 hasConcept C42360764 @default.
• W2034187009 hasConcept C43411465 @default.
• W2034187009 hasConcept C502130503 @default.
• W2034187009 hasConcept C515602321 @default.
• W2034187009 hasConcept C516920438 @default.
• W2034187009 hasConcept C544153396 @default.
• W2034187009 hasConceptScore W2034187009C127413603 @default.
• W2034187009 hasConceptScore W2034187009C161790260 @default.
• W2034187009 hasConceptScore W2034187009C178790620 @default.
• W2034187009 hasConceptScore W2034187009C179104552 @default.
• W2034187009 hasConceptScore W2034187009C185592680 @default.
• W2034187009 hasConceptScore W2034187009C192562407 @default.
• W2034187009 hasConceptScore W2034187009C2777961443 @default.
• W2034187009 hasConceptScore W2034187009C2778077586 @default.
• W2034187009 hasConceptScore W2034187009C2780026712 @default.
• W2034187009 hasConceptScore W2034187009C42360764 @default.
• W2034187009 hasConceptScore W2034187009C43411465 @default.
• W2034187009 hasConceptScore W2034187009C502130503 @default.
• W2034187009 hasConceptScore W2034187009C515602321 @default.
• W2034187009 hasConceptScore W2034187009C516920438 @default.
• W2034187009 hasConceptScore W2034187009C544153396 @default.
• W2034187009 hasIssue "10" @default.
• W2034187009 hasLocation W20341870091 @default.
• W2034187009 hasOpenAccess W2034187009 @default.
• W2034187009 hasPrimaryLocation W20341870091 @default.
• W2034187009 hasRelatedWork W1999600664 @default.
• W2034187009 hasRelatedWork W2005715228 @default.
• W2034187009 hasRelatedWork W2068458301 @default.
• W2034187009 hasRelatedWork W2072518499 @default.

• next