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- W2034189612 abstract "The E/Z -Photoisomerization of Schiff bases N,N' -bis(4-dimethylamino benzylidene)1,2-diaminoethane (BDAE) and N,N' -bis(4-dimethylaminobenzyli-dene)1,3-diaminopropane (BDAP) were studied by UV-Vis absorption spectroscopy and theoretical chemistry calculations. Photochemical investigations in solution depict the time resolved spectral changes, recorded before and after irradiation. The shift indicates the transformation from E to Z configuration of the C=N bond in solution for BDAE and BDAP. Spectra profiles and kinetic constants were evaluated using multivariate curve resolution and non-linear least squares curve fitting by toolbox of MATLAB program using the corresponding absorption spectra-time data. The experimental results show that BDAP can perform the photochromism easier than BDAE, may be due to the molecular topology difference." @default.
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- W2034189612 date "2011-01-01" @default.
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- W2034189612 title "<i>E/Z</i>-Photoisomerization of<i>N,N'</i>-Bis(4-dimethylaminobenzylidene)1,2-diaminoethane and<i>N,N'</i>-Bis(4-dimethylaminobenzylidene)1,3-diaminopropane in Chloroform" @default.
- W2034189612 cites W1966515625 @default.
- W2034189612 doi "https://doi.org/10.1155/2011/918589" @default.
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