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• W2034192549 endingPage "4936" @default.
• W2034192549 startingPage "4933" @default.
• W2034192549 abstract "The reaction of SnCl2 with C5Ph5Cl produces C5Ph5SnCl3 (1) in an oxidative-addition reaction, while the pentaphenylcyclopentadienyl radical, C5Ph5•, (2) is obtained in the reactions of C5Ph5Br with SnCl2 or SnBr2 in diethyl ether/tetrahydrofuran (THF). In the reaction of SnCl2 with C5Ph5Br, one of the tin halide products was shown to be SnBrCl(THF)2 (3). The molecular structures of compounds 1−3 were determined by X-ray crystallography. Tin compound 1 is σ-bonded to the cyclopentadienyl ring; the radical 2 features a planar C5 ring, and the structure of 3 consists of SnBrCl units coordinated by two THF molecules with an apparent stereochemical activity of the tin lone pair." @default.
• W2034192549 created "2016-06-24" @default.
• W2034192549 creator A5055392457 @default.
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• W2034192549 creator A5090644272 @default.
• W2034192549 date "1997-10-01" @default.
• W2034192549 modified "2023-09-26" @default.
• W2034192549 title "Structures of the Pentaphenylcyclopentadienyl Radical, (Pentaphenylcyclopentadienyl)tin(IV) Trichloride, and Bromo(chloro)bis(tetrahydrofuran)tin(II): Products of the Reaction of C₅Ph₅X with SnX₂ (X = Cl, Br)" @default.
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• W2034192549 doi "https://doi.org/10.1021/om970442s" @default.
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