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• W2034193746 endingPage "1742" @default.
• W2034193746 startingPage "1735" @default.
• W2034193746 abstract "Terminally blocked, syndiotactic linear homo-peptides from Cα,α-disubstituted glycines Iva and (αMe)Val have been prepared to the hexapeptide and tripeptide amide levels, respectively, by solution methods and fully characterized. The molecular and crystal structures of pBrBz-(D-lva-L-lva)2-OBut methanol solvate, pBrBz-(D-lva-L-lva)2-D-lva-OBut methanol solvate, and Z-D-(αMe)Val-L-(aMe)Val-D-(aMe)Val-NHPri(pBrBz =p-bromobenzoyl, Z = benzyloxycarbonyl) were determined by X-ray diffraction. While the Iva pentapeptide and the (αMe) Val tripeptide amide are folded in an (incipient) left-handed 310-helical conformation, the Iva tetrapeptide adopts a double β-bend conformation of the II′–III type. The FTIR absorption and 1H NMR analyses support our contention that in chloroform solution, the longest syndiotactic homo-peptides may be folded in well developed 310-helical structures. This is the first structural study reported on regularly alternating (D–L) peptides based on conformationally constrained α-amino acids." @default.
• W2034193746 created "2016-06-24" @default.
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• W2034193746 date "1994-01-01" @default.
• W2034193746 modified "2023-10-03" @default.
• W2034193746 title "Linear oligopeptides. Part 316. Conformational characterization of syndiotactic homo-peptides from C^α,α-disubstituted glycines" @default.
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• W2034193746 doi "https://doi.org/10.1039/p29940001735" @default.
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