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• W2034194534 abstract "The work described here demonstrates that the five-membered cyclic α-methylisoserine-derived sulfamidate, (R)-1, behaves as an excellent chiral building block for the ring-opening reaction by SN2 attack with sulfur nucleophiles at the quaternary carbon. As a synthetic application of this methodology, and to show that this sulfamidate is a valuable starting material, the synthesis of two new α-methylisocysteine derivatives has been carried out to cover the lack of α- and β-methylated amino acids that incorporate the cysteine or isocysteine skeleton. These compounds are two new α,α-disubstituted β-amino acids (β2,2-amino acids), and the synthetic routes involve nucleophilic ring opening followed by acid hydrolysis." @default.
• W2034194534 created "2016-06-24" @default.
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• W2034194534 date "2006-01-13" @default.
• W2034194534 modified "2023-09-25" @default.
• W2034194534 title "S_N2 Reaction of Sulfur Nucleophiles with Hindered Sulfamidates: Enantioselective Synthesis of α-Methylisocysteine" @default.
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• W2034194534 doi "https://doi.org/10.1021/jo051632c" @default.
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