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• W2034194768 endingPage "11" @default.
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• W2034194768 abstract "Two new ruthenium(II) mixed ligand terpyridine complexes, “Ru(Htcterpy)(NCS)( L1 ) (N(C 4 H 9 ) 4 ), m LBD1 ” and Ru(Htcterpy)(NCS)( L2 )(N(C 4 H 9 ) 4 ), m LBD2 were synthesized and fully characterized by UV-Vis, emission, cyclic voltammogram, and other spectroscopic means, and the structures of the compounds are confirmed by 1 H-NMR, ESI-MASS, and FT-IR spectroscopes. The influence of the substitution of L1 and L2 on solar-to-electrical energy conversion efficiency ( η ) of dye-sensitized solar cells (DSSCs) was evaluated relative to reference black dye. The dyes showed molar extinction coefficients of 17600 M −1 cm −1 for m LBD1 and 21300 M −1 cm −1 for m LBD2 both at λ maximum of 512 nm, while black dye has shown 8660 M −1 cm −1 at λ maximum of 615 nm. The monochromatic incident photon-to-collected electron conversion efficiencies of 60.71% and 75.89% were obtained for m LBD1 and m LBD2 dyes, respectively. The energy conversion efficiencies of m LBD1 and m LBD2 dyes are 3.15% ( mA/cm 2 , mV, ) and 3.36% ( mA/cm 2 , mV, ), respectively, measured at the AM1.5G conditions, the reference black dye-sensitized solar cell, fabricated and evaluated under identical conditions exhibited η -value of 2.69% ( mA/cm 2 , mV, )." @default.
• W2034194768 created "2016-06-24" @default.
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• W2034194768 date "2011-08-22" @default.
• W2034194768 modified "2023-09-27" @default.
• W2034194768 title "High Molar Extinction Coefficient Ru(II)-Mixed Ligand Polypyridyl Complexes for Dye Sensitized Solar Cell Application" @default.
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• W2034194768 doi "https://doi.org/10.1155/2011/432803" @default.
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