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- W2034195318 abstract "The formation, structure, and dynamics of planar organometallic macrocycles (meta-terphenyl-Cu)n and zigzag-shaped one-dimensional organometallic polymers on a Cu(111) surface were studied with scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). Vapor deposition of 4,4″-dibromo-meta-terphenyl (DMTP) onto Cu(111) at 300 K leads to C–Br bond scission and formation of C–Cu–C bonds, which connect neighboring meta-terphenyl fragments such that room-temperature stable macrocycles and zigzag chains are formed. The chains self-assemble to form islands, which are elongated in the direction of the chains. If DMTP is deposited onto Cu(111) held at 440 K, the island size is drastically increased (>200 × 200 nm2). STM sequences show the formation of ordered structures through reversible scission and reformation of the C–Cu–C bonds. The cyclic organometallic species such as the hexamer (meta-terphenyl-Cu)6 may represent intermediates in the surface-confined Ullmann synthesis of hydrocarbon macrocycles such as the recently discovered hyperbenzene." @default.
- W2034195318 created "2016-06-24" @default.
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- W2034195318 date "2013-12-16" @default.
- W2034195318 modified "2023-09-28" @default.
- W2034195318 title "Surface-Assisted Formation, Assembly, and Dynamics of Planar Organometallic Macrocycles and Zigzag Shaped Polymer Chains with C–Cu–C Bonds" @default.
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- W2034195318 doi "https://doi.org/10.1021/nn405370s" @default.
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