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• W2034198300 abstract "The kinetics and mechanism of the disproportionation of MnO(4)(-) via [CMC-MnVIO(4)(2-)] intermediate complex formation during the oxidation of carboxymethyl-cellulose (CMC) polysaccharide have been investigated spectrophotometrically at pH>/=12 and various temperatures (15-35 degrees C). The rate law was suggested as rate=k(obs)[MnO(4)(-)]. Kinetic and spectrophotometric measurements revealed the base-catalyzed formation of manganate(VI) transient species. A mechanism was postulated consistent with the experimental data. Copyright 2001 Academic Press." @default.
• W2034198300 created "2016-06-24" @default.
• W2034198300 creator A5009862050 @default.
• W2034198300 date "2001-01-01" @default.
• W2034198300 modified "2023-09-27" @default.
• W2034198300 title "Base-Catalyzed Oxidation of Carboxymethyl-cellulose Polymer by Permanganate" @default.
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• W2034198300 doi "https://doi.org/10.1006/jcis.2000.7246" @default.
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