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- W2034198404 abstract "Sequential Diels-Alder additions of methylvinyl ketone and dehydrobenzene to 2, 3, 5, 6-tetramethylidene-7-oxanorbornane (4) yielded the (5, 12-epoxy-1, 2, 3, 4, 5, 6, 11, 12-octahydro-2-naphtacenyl) methyl ketone (10) which, in few steps was oxidized to a precursos of (±)-4-demethoxydaunomycinone. The preparations of two precursors of anthracyclinones, the (5-acetoxy-) and (12-acetoxy-1, 2, 3, 4-tetrahydro-2-naphtacenyl) methyl ketones (14, 15) are presented. The synthesis of 6, 13-epoxy-6, 13-dihydropentacene (8) is also reported." @default.
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- W2034198404 date "1980-01-23" @default.
- W2034198404 modified "2023-10-16" @default.
- W2034198404 title "Synthesis of (±)-4-Demethoxydaunomycinone by Double<i>Diels-Alder</i>Additions to 2, 3, 5, 6-Tetramethylidene-7-oxanorbornane" @default.
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- W2034198404 doi "https://doi.org/10.1002/hlca.19800630123" @default.
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