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- W2034203019 abstract "The kinetics of oxidation of a number of ortho, meta, and para substituted S-phenylmercaptoacetic acids by N-Chloro-3-Metyl-2,6-Diphenylpiperidin-4-one (NCP) has been studied in buffered ethanol-water (75:25 v/v) of pH 5.46. The reaction is of first order each in [oxidant] and [substrate]. The rate constant decreases with increase in pH from 5.22 to 5.70. The reaction is accelerated by electron releasing and retarded by electron withdrawing substitutents. The ρ value obtained for this reaction is −1.88 at 10°C with a good correlation coefficient of 0.99 showing an electron deficient transition state. The effect of ortho substitutents also is discussed in detail." @default.
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- W2034203019 date "1989-06-01" @default.
- W2034203019 modified "2023-10-14" @default.
- W2034203019 title "Kinetics of oxidation of some ortho, meta, and para substitutedS-phenylmercaptoacetic Acids byN-Chloro-3-Methyl-2,6-Diphenyl piperidin-4-one in buffered ethanol-water" @default.
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- W2034203019 doi "https://doi.org/10.1002/kin.550210605" @default.
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