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- W2034204096 abstract "Novel 1,3-alternate calix[4]azacrowns having an azo chromophoric pendent group were synthesized, and their 1,3-alternate conformations were confirmed by X-ray crystal structure. In view of the hypsochromical UV band shifting upon cation complexation, azo-coupled calix[4]azacrown-5 (3) showed the most selective shifting with alkali and alkaline metal ions. In addition, 3 revealed K+ ion selectivity not only due to the size comparability between the K+ ion and the azacrown-5 loop but also due to a significant K+-pi interaction between the two aromatic rings and the K+ ion. The UV band shifting is also dependent on the lipophilicity of the species of counteranion used." @default.
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- W2034204096 date "2002-01-24" @default.
- W2034204096 modified "2023-09-23" @default.
- W2034204096 title "Chromogenic Azo-Coupled Calix[4]arenes" @default.
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- W2034204096 doi "https://doi.org/10.1021/jo0108921" @default.
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