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- W2034207186 abstract "Phase relations in the system Ni–Sb–Te were studied in evacuated silica glass tubes to construct the 400°C isothermal section. Two extensive ternary solid-solutions were detected in the system, λ1, Ni(Sb1– x Te x )1+ y (0 < x < 1, where, for x ≥ 0.9, the relation 0.09 ≤ y ≤ 1 applies), and λ2, NiSb1– x Te2 x (0.28 < x < 0.66). Their stability fields are elongate along the NiTe1.09–NiSb and NiSb–NiTe2 joins, respectively, indicating extensive Sb-for-Te substitution. These two solid solutions are breakdown products of the broad NiSb–NiTe–NiTe2 solid solution that dominates the system at temperatures higher than 690°C. The mineral vavřinite, Ni2SbTe2, is a part of the λ2 solid solution at 400°C. The average crystal structure of the λ2 solid solution is of the CdI2-or NiAs-type at 400°C; Sb and Te atoms occupy the same crystallographic position ( i.e. , Sb,Te mixed site). The λ1 solid solution displays the NiAs-type structure along the NiTe1.09–NiSb join; toward NiTe2 composition, the phase was found to be of the CdI2 type. Nisbite, NiSb2, dissolves 8.4 at.% Te at 400°C. Phases Ni7Sb3, β2 (Ni3–δTe2), γ1 (NiTe0.775) and A (Ni5.66SbTe2), hitherto unknown as minerals, can be expected in mafic and ultramafic rocks, in close association with melonite and breithauptite." @default.
- W2034207186 created "2016-06-24" @default.
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- W2034207186 date "2010-10-01" @default.
- W2034207186 modified "2023-09-28" @default.
- W2034207186 title "THE SYSTEM Ni-Sb-Te AT 400 C" @default.
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- W2034207186 doi "https://doi.org/10.3749/canmin.48.5.1069" @default.
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