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- W2034213992 abstract "Quantum state-resolved sticking coefficients on Pt(111) and Ni(111) surfaces have been measured for CH4 excited to the first overtone of the antisymmetric C-H stretch (2nu3) at well-defined kinetic energies in the range of 10-90 kJ/mol. The ground-state reactivity of CH4 is approximately 3 orders of magnitude lower on Ni(111) than on Pt(111) for kinetic energies in the range of 10-64 kJ/mol, reflecting a difference in barrier height of 28+/-6 kJ/mol. 2nu3 excitation of CH4 increases its reactivity by more than 4 orders of magnitude on Ni(111), whereas on Pt(111) the reactivity increase is lower by 2 orders of magnitude. We discuss the observed differences in the state-resolved reactivity for the ground state and 2nu3 excited state of methane in terms of a difference in barrier height and transition state location for the dissociation reaction on the two metal surfaces." @default.
- W2034213992 created "2016-06-24" @default.
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- W2034213992 date "2007-11-14" @default.
- W2034213992 modified "2023-10-13" @default.
- W2034213992 title "State-Resolved Reactivity of CH<sub>4</sub>(2ν<sub>3</sub>) on Pt(111) and Ni(111): Effects of Barrier Height and Transition State Location" @default.
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- W2034213992 doi "https://doi.org/10.1021/jp076082w" @default.
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