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- W2034215248 endingPage "2506" @default.
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- W2034215248 abstract "The reaction of ytterbium metal, HgPh2 and N-(2-methoxyphenyl)-N-(trimethylsilyl)amine (L1H) or N-(2-phenoxyphenyl)-N-(trimethylsilyl)amine (L2H) in tetrahydrofuran (thf) unexpectedly yielded the ytterbium(III) complexes [Yb(L1)2(μ-OMe)]2 (1) and [Yb(L2)2(OPh)(thf)] (2), the structures of which were established by X-ray crystallography. These are considered to be derived from C−O bond cleavage of the ligand aryl ether moiety by an initially formed YbII species, e.g. the thermally unstable, but crystallographically authenticated [Yb(L1)2(thf)2] (3), which was independently prepared from [Yb{N(SiMe3)2}2(thf)2] and L1H." @default.
- W2034215248 created "2016-06-24" @default.
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- W2034215248 date "2000-12-01" @default.
- W2034215248 modified "2023-09-25" @default.
- W2034215248 title "Aryl Ether C−O Bond Activation by Organoamidolanthanoid(II) Complexes" @default.
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- W2034215248 doi "https://doi.org/10.1002/1099-0682(200012)2000:12<2501::aid-ejic2501>3.0.co;2-w" @default.
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