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• W2034222163 abstract "A series of structurally related β-amino alcohols only differing in the steric bulk of a remote alkoxy group exhibit striking differences in kinetic behavior when used as ligands in the asymmetric diethylzinc addition to benzaldehyde (R = Trityl, much more active). A combination of NMR titration studies and kinetic analysis allows the quantitative decomposition of the remote substituent effect into a lower dimerization constant of the active species and a much faster ethyl addition step." @default.
• W2034222163 created "2016-06-24" @default.
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• W2034222163 date "2006-08-01" @default.
• W2034222163 modified "2023-10-17" @default.
• W2034222163 title "Ligand Anatomy: Probing Remote Substituent Effects in Asymmetric Catalysis through NMR and Kinetic Analysis" @default.
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• W2034222163 doi "https://doi.org/10.1021/ol0612197" @default.
• W2034222163 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16928032" @default.
• W2034222163 hasPublicationYear "2006" @default.
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