FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034222578> ?p ?o ?g. }

• W2034222578 endingPage "179" @default.
• W2034222578 startingPage "169" @default.
• W2034222578 abstract "A series of new alkoxy-amino-bis(phenols) (H2L 1–6) has been synthesized by Mannich condensations of substituted phenols, formaldehyde, and amino ethers or diamines. The coordination properties of these dianionic ligands towards yttrium, lanthanum, and neodymium have been studied. The resulting Group 3 metal complexes have been used as initiators for the ring-opening polymerization of rac-lactide to provide poly(lactic acid)s (PLAs). The polymerizations are living, as evidenced by the narrow polydispersities of the isolated polymers, together with the linear natures of number average molecular weight versus conversion plots and monomer-to-catalyst ratios. Complex [Y(L6){N(SiHMe2)2}(THF)] (17) polymerized rac-lactide to heterotactic PLA (Pr = 0.90 at 20 °C) and meso-lactide to syndiotactic PLA (Pr = 0.75 at 20 °C). The in situ formation of [Y(L6)(OiPr)(THF)] (18) from 17 and 2-propanol resulted in narrower molecular weight distributions (PDI = 1.06). With complex 18, highly heterotactic PLAs with narrow molecular weight distributions were obtained with high activities and productivities at room temperature. The natures of the ligand substituents were shown to have a significant influence on the degree of control of the polymerizations, and in particular on the tacticity of the polymer." @default.
• W2034222578 created "2016-06-24" @default.
• W2034222578 creator A5049143428 @default.
• W2034222578 creator A5049801841 @default.
• W2034222578 creator A5064611725 @default.
• W2034222578 creator A5076564450 @default.
• W2034222578 date "2006-01-01" @default.
• W2034222578 modified "2023-10-18" @default.
• W2034222578 title "Ring-Opening Polymerization of Lactide with Group 3 Metal Complexes Supported by Dianionic Alkoxy-Amino-Bisphenolate Ligands: Combining High Activity, Productivity, and Selectivity" @default.
• W2034222578 cites W1623501845 @default.
• W2034222578 cites W1893192753 @default.
• W2034222578 cites W1963911840 @default.
• W2034222578 cites W1967984957 @default.
• W2034222578 cites W1969635440 @default.
• W2034222578 cites W1972973218 @default.
• W2034222578 cites W1978829998 @default.
• W2034222578 cites W1981514688 @default.
• W2034222578 cites W1981810075 @default.
• W2034222578 cites W1983604746 @default.
• W2034222578 cites W1983778067 @default.
• W2034222578 cites W1985088426 @default.
• W2034222578 cites W1985570466 @default.
• W2034222578 cites W1987289038 @default.
• W2034222578 cites W1987896209 @default.
• W2034222578 cites W1988087684 @default.
• W2034222578 cites W1991128442 @default.
• W2034222578 cites W1991648807 @default.
• W2034222578 cites W1995880600 @default.
• W2034222578 cites W1999934105 @default.
• W2034222578 cites W2000855711 @default.
• W2034222578 cites W2004721157 @default.
• W2034222578 cites W2006395860 @default.
• W2034222578 cites W2006562372 @default.
• W2034222578 cites W2011920266 @default.
• W2034222578 cites W2016077890 @default.
• W2034222578 cites W2021753261 @default.
• W2034222578 cites W2023023358 @default.
• W2034222578 cites W2023170224 @default.
• W2034222578 cites W2025650969 @default.
• W2034222578 cites W2027210775 @default.
• W2034222578 cites W2031182629 @default.
• W2034222578 cites W2032325663 @default.
• W2034222578 cites W2034604173 @default.
• W2034222578 cites W2035200786 @default.
• W2034222578 cites W2036064935 @default.
• W2034222578 cites W2041546233 @default.
• W2034222578 cites W2045541174 @default.
• W2034222578 cites W2047814327 @default.
• W2034222578 cites W2050687820 @default.
• W2034222578 cites W2051729429 @default.
• W2034222578 cites W2056712666 @default.
• W2034222578 cites W2060280373 @default.
• W2034222578 cites W2060885524 @default.
• W2034222578 cites W2061088416 @default.
• W2034222578 cites W2061667657 @default.
• W2034222578 cites W2063877102 @default.
• W2034222578 cites W2065389010 @default.
• W2034222578 cites W2065579325 @default.
• W2034222578 cites W2066379496 @default.
• W2034222578 cites W2073294903 @default.
• W2034222578 cites W2079669276 @default.
• W2034222578 cites W2080646078 @default.
• W2034222578 cites W2082189380 @default.
• W2034222578 cites W2082264584 @default.
• W2034222578 cites W2083282609 @default.
• W2034222578 cites W2085843225 @default.
• W2034222578 cites W2090994478 @default.
• W2034222578 cites W2092337099 @default.
• W2034222578 cites W2092999693 @default.
• W2034222578 cites W2095372317 @default.
• W2034222578 cites W2097501047 @default.
• W2034222578 cites W2103986047 @default.
• W2034222578 cites W2108463100 @default.
• W2034222578 cites W2111283164 @default.
• W2034222578 cites W2114683712 @default.
• W2034222578 cites W2135848862 @default.
• W2034222578 cites W2139636274 @default.
• W2034222578 cites W2141860146 @default.
• W2034222578 cites W2142878028 @default.
• W2034222578 cites W2145587477 @default.
• W2034222578 cites W2152476602 @default.
• W2034222578 cites W2165822172 @default.
• W2034222578 cites W2170498612 @default.
• W2034222578 cites W2319542431 @default.
• W2034222578 cites W2474579450 @default.
• W2034222578 cites W3005116629 @default.
• W2034222578 doi "https://doi.org/10.1002/chem.200500856" @default.
• W2034222578 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16224808" @default.
• W2034222578 hasPublicationYear "2006" @default.
• W2034222578 type Work @default.
• W2034222578 sameAs 2034222578 @default.
• W2034222578 citedByCount "381" @default.
• W2034222578 countsByYear W20342225782012 @default.
• W2034222578 countsByYear W20342225782013 @default.
• W2034222578 countsByYear W20342225782014 @default.
• W2034222578 countsByYear W20342225782015 @default.
• W2034222578 countsByYear W20342225782016 @default.
• W2034222578 countsByYear W20342225782017 @default.

• next