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- W2034223868 abstract "The interaction between poly(acrylic acid) (PAA) and oxyethylene oligomers (PEG) was investigated by solution microcalorimetry in water at 25°C. The enthalpy of interaction is endothermic, and, in the case of PEG-400 in large excess, the enthalpic parameter increases sharply with PEG/PAA ratio. No such behaviour was found for PEG-1000 and for dimethylated PEG-400. The apparent monomolar heat capacity of the binary solute was also determined, and the corresponding excess quantity is negative at any PEG/PAA ratio. The two series of microcalorimetric results indicate that PAA and oxyethylene oligomers interact noticeably in water and that a long PAA chain may be regarded as a linear adsorption surface for short PEG chains." @default.
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- W2034223868 date "1990-10-01" @default.
- W2034223868 modified "2023-10-03" @default.
- W2034223868 title "Microcalorimetric investigation on interaction between poly(acrylic acid) and oxyethylene oligomers in water" @default.
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- W2034223868 doi "https://doi.org/10.1016/0032-3861(90)90021-p" @default.
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