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- W2034228809 abstract "Elastic properties of different compositions of lithium borate glasses xLi2O·(1-x)B2O3 (x=0.06–0.28) were investigated in the temperature range from 25 to 600 °C by Brillouin scattering spectroscopy. The composition dependence of the lithium borate glass system shows a stiffening tendency and a higher onset temperature of softening with increasing mole fraction of Li2O. We successfully observed the change in longitudinal elastic modulus in the vicinity of the glass transition temperature (Tg). The elastic moduli show a marked temperature dependence above the glass transition temperature Tg, while they show little change below Tg. These results strongly relate to the structural conversion of cross-linking borate units from triangular BO3 to tetrahedral BO4 units by the addition of Li2O. The increase in lithium oxide enhances the glass network integrity in the composition range of this study. A significant decrease in the elastic modulus above Tg can be attributed to the association of boroxol ring deformation and a change in the coordination number of boron atoms. These elastic properties were discussed in comparison with lithium silicate glass." @default.
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- W2034228809 date "2006-05-25" @default.
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- W2034228809 title "Brillouin Scattering Study of Liquid Glass Transition in Lithium Borate Glass" @default.
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- W2034228809 doi "https://doi.org/10.1143/jjap.45.4474" @default.
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