FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034228962> ?p ?o ?g. }

• W2034228962 endingPage "3667" @default.
• W2034228962 startingPage "3655" @default.
• W2034228962 abstract "Treatment of the chloro-bridged dinuclear complex [Pd{3,4-(MeO)2C6H2C(H)N(Cy)-C6,N}(μ-Cl)]2 (1) with homobidentate [P,P], [As,As], [N,N], and heterobidentate [P,As], [P,N] ligands in a 1:1 molar ratio gave the dinuclear complexes [{Pd[3,4-(MeO)2C6H2C(H)N(Cy)-C6,N](Cl)}2{μ-L}] (L = Ph2PC4H6(NH)CH2PPh2 (2); Ph2As(CH2)2AsPh2 (3); 1,3-(NH2CH2)2C6H4 (4); Ph2P(CH2)2AsPh2 (5); Ph2P(CH2)2NH2 (6)), with the bidentate ligands bridging the two cyclometallated fragments. The reaction with the homobidentate ligands in a 1:2 molar ratio in the presence of NaClO4 afforded the mononuclear compounds [[Pd{3,4-(MeO)2C6H2C(H)N(Cy)-C6,N}{L-P,P}][ClO4] (L = Ph2PC4H6(NH)CH2PPh2 (7); (o-Tol)2P(CH2)2P(o-Tol)2 (8)), [Pd{3,4-(MeO)2C6H2C(H)N(Cy)-C6,N}{Ph2As(CH2)2AsPh2-As,As}][ClO4] (9) and [Pd{3,4-(MeO)2C6H2C(H)N(Cy)-C6,N}{L-N,N}][ClO4] (L = NH2(CH2)3NH2 (10); NH2(C6H8)CH2(C6H8)NH2 (11); 1,3-(NH2CH2)2C6H4 (12); 1,3-(NH2)2C5H3N (13); NH2(C6H4)O(C6H4)NH2 (14); NMe2(CH2)2NMe2 (15)), in which the chloro ligands are absent and the bidentate ligands are chelated to the palladium atom. Reaction of 1 with Ph2P(CH2)2AsPh2 in 1:2 molar ratio in acetone in the presence of NH4PF6 afforded the analogous mononuclear compound [Pd{3,4-(MeO)2C6H2C(H)N(Cy)-C6,N}{Ph2P(CH2)2AsPh2-P,As}][PF6] (16); whereas reaction with Ph2P(CH2)3NH2 gave [Pd{3,4-(MeO)2C6H2C(H)N(Cy)-C6,N}{Ph2P(CH2)3N(CMe2)-P,N}][PF6] (17), derived from intermolecular condensation between the aminophosphine and acetone. Condensation of the NH2 group was precluded by change of solvent, using dichloromethane. Iminophoshines also reacted with 1 in 1:2 molar ratio in acetone to give a new series of mononuclear cyclometallated complexes: [Pd{3,4-(MeO)2C6H2C(H)N(Cy)-C6,N}{L-P,N}][ClO4] (L = Ph2PC6H4C(H)NCy (20); Ph2PC6H4C(H)NC(CH3)3 (21); Ph2PC6H4C(H)NNMe2 (22); Ph2PC6H4C(H)NNHMe (23); Ph2PC6H4C(H)NNHPh (24)). Analogous complexes with a stable P,O-chelate were obtained using bidentate [P,O] donor ligands: [Pd{3,4-(MeO)2C6H2C(H)N(Cy)-C6,N}{L-P,O}][Cl] (L = 2-(Ph2P)C6H4CHO (25); Ph2PN(Me)C(O)Me (26)). The crystal structures of compounds 1, 5, 15, 16, 18, 20 have been determined by X-ray crystallography." @default.
• W2034228962 created "2016-06-24" @default.
• W2034228962 creator A5037848048 @default.
• W2034228962 creator A5039597665 @default.
• W2034228962 creator A5045008148 @default.
• W2034228962 creator A5055621199 @default.
• W2034228962 creator A5069798762 @default.
• W2034228962 creator A5075266867 @default.
• W2034228962 creator A5084717845 @default.
• W2034228962 date "2008-11-01" @default.
• W2034228962 modified "2023-10-18" @default.
• W2034228962 title "Synthesis, characterization and crystal structures of cyclometallated palladium (II) compounds containing difunctional ligands with [P,P], [As,As], [N,N], [P,As], [P,N] and [P,O] donor atoms" @default.
• W2034228962 cites W116144525 @default.
• W2034228962 cites W1964368379 @default.
• W2034228962 cites W1967058645 @default.
• W2034228962 cites W1968589663 @default.
• W2034228962 cites W1972197907 @default.
• W2034228962 cites W1973783563 @default.
• W2034228962 cites W1974270223 @default.
• W2034228962 cites W1981009723 @default.
• W2034228962 cites W1981754097 @default.
• W2034228962 cites W1983602594 @default.
• W2034228962 cites W1986251976 @default.
• W2034228962 cites W1989751879 @default.
• W2034228962 cites W1996597708 @default.
• W2034228962 cites W1997861101 @default.
• W2034228962 cites W1998722626 @default.
• W2034228962 cites W1998743991 @default.
• W2034228962 cites W2000994711 @default.
• W2034228962 cites W2014668425 @default.
• W2034228962 cites W2015916935 @default.
• W2034228962 cites W2019316265 @default.
• W2034228962 cites W2021911876 @default.
• W2034228962 cites W2026201389 @default.
• W2034228962 cites W2029140525 @default.
• W2034228962 cites W2031355550 @default.
• W2034228962 cites W2032139582 @default.
• W2034228962 cites W2032855674 @default.
• W2034228962 cites W2035409838 @default.
• W2034228962 cites W2041144870 @default.
• W2034228962 cites W2045049250 @default.
• W2034228962 cites W2046070709 @default.
• W2034228962 cites W2055348009 @default.
• W2034228962 cites W2057880346 @default.
• W2034228962 cites W2057993527 @default.
• W2034228962 cites W2061690880 @default.
• W2034228962 cites W2063053394 @default.
• W2034228962 cites W2069580292 @default.
• W2034228962 cites W2070481472 @default.
• W2034228962 cites W2072869867 @default.
• W2034228962 cites W2073204029 @default.
• W2034228962 cites W2073881108 @default.
• W2034228962 cites W2075346893 @default.
• W2034228962 cites W2078416574 @default.
• W2034228962 cites W2080028840 @default.
• W2034228962 cites W2080760337 @default.
• W2034228962 cites W2084783229 @default.
• W2034228962 cites W2086939053 @default.
• W2034228962 cites W2090000918 @default.
• W2034228962 cites W2092039993 @default.
• W2034228962 cites W2092610832 @default.
• W2034228962 cites W2095097978 @default.
• W2034228962 cites W2133491622 @default.
• W2034228962 cites W2158672429 @default.
• W2034228962 cites W2201931770 @default.
• W2034228962 cites W2318364212 @default.
• W2034228962 cites W2321355563 @default.
• W2034228962 cites W2321386849 @default.
• W2034228962 cites W2321624598 @default.
• W2034228962 cites W2951668360 @default.
• W2034228962 cites W4256234511 @default.
• W2034228962 cites W66165689 @default.
• W2034228962 cites W74218690 @default.
• W2034228962 doi "https://doi.org/10.1016/j.jorganchem.2008.08.023" @default.
• W2034228962 hasPublicationYear "2008" @default.
• W2034228962 type Work @default.
• W2034228962 sameAs 2034228962 @default.
• W2034228962 citedByCount "12" @default.
• W2034228962 countsByYear W20342289622012 @default.
• W2034228962 countsByYear W20342289622013 @default.
• W2034228962 countsByYear W20342289622016 @default.
• W2034228962 countsByYear W20342289622017 @default.
• W2034228962 crossrefType "journal-article" @default.
• W2034228962 hasAuthorship W2034228962A5037848048 @default.
• W2034228962 hasAuthorship W2034228962A5039597665 @default.
• W2034228962 hasAuthorship W2034228962A5045008148 @default.
• W2034228962 hasAuthorship W2034228962A5055621199 @default.
• W2034228962 hasAuthorship W2034228962A5069798762 @default.
• W2034228962 hasAuthorship W2034228962A5075266867 @default.
• W2034228962 hasAuthorship W2034228962A5084717845 @default.
• W2034228962 hasConcept C115624301 @default.
• W2034228962 hasConcept C155647269 @default.
• W2034228962 hasConcept C161790260 @default.
• W2034228962 hasConcept C178516000 @default.
• W2034228962 hasConcept C178790620 @default.
• W2034228962 hasConcept C185592680 @default.
• W2034228962 hasConcept C197404232 @default.
• W2034228962 hasConcept C2994067411 @default.

• next