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- W2034229238 abstract "A series of crown ether type binaphthyl derivatives (CEBDs) were synthesized and used as chiral dopants to induce chiral nematic (N*) liquid crystals (LCs). The twisting powers of the CEBDs for phenylcyclohexane (PCH)-derived nematic LCs were evaluated. It was found that the twisting powers of the CEBDs increased with decreasing ring size of the crown ether. Helical polyacetylenes were synthesized in the N*-LCs induced by the CEBDs. The relationship between the morphology of the helical polyacetylene and the helical structure of the N*-LC was investigated. The result showed that the interdistance between the fibril bundles of the helical polyacetylene was equal to a half-helical pitch of the N*-LC and the screw direction of the polyacetylene fibrils was opposite to that of the N*-LC." @default.
- W2034229238 created "2016-06-24" @default.
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- W2034229238 date "2005-10-01" @default.
- W2034229238 modified "2023-10-13" @default.
- W2034229238 title "Synthesis of Helical Polyacetylene in Chiral Nematic Liquid Crystals Using Crown Ether Type Binaphthyl Derivatives as Chiral Dopants" @default.
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- W2034229238 doi "https://doi.org/10.1021/ja051548e" @default.
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