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- W2034229771 abstract "Different glasses with nominal compositions of (70 − x)V2O5–xPbO–20Li2O–10Fe2O3 (0 ≤ x ≤ 12.5 mol.%) were successfully obtained by the melt quenching technique. Crystallization kinetics of these glasses was studied under non-isothermal conditions using the formal theory of transformations for heterogeneous nucleation. The procedure was applied to the experimental data obtained by differential thermal analysis, using several measurements at different heating rates. In addition, from the heating rate dependence of the glass transition temperature, the glass transition activation energy was derived. The crystallization results are analyzed and both the activation energy of crystallization process and the crystallization mechanism are characterized in terms of Gao–Wang method. The phases at which the glass crystallizes after the thermal process have been identified by X-ray diffraction. The diffractogram of the transformed material indicates the presence of microcrystallites of LiV15O35.5, Pb3(VO4)2 and PbO2 beside the remaining an additional amorphous matrix." @default.
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- W2034229771 date "2009-08-01" @default.
- W2034229771 modified "2023-09-26" @default.
- W2034229771 title "Crystallization kinetics of new compound of V2O5–PbO–Li2O–Fe2O3 glass using differential thermal analysis" @default.
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- W2034229771 doi "https://doi.org/10.1016/j.jallcom.2009.04.062" @default.
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