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- W2034234653 abstract "Abstract Lewis acid-catalyzed reaction of acetals with allenylsilanes and the three-component reactions of aldehydes, alkoxysilanes, and allenylsilanes are described. Both reactions are strongly dependent on the substituent at the α-position of allenylsilanes. Allenylsilanes having bulky substituents such as the tert-butyl and isopropyl groups result in the corresponding α-propargyl ethers in high yields, whereas allenylsilanes having the methyl and ethyl groups afford not only the corresponding α-propargyl ethers in low yield but also cyclopropyl ketones and α,β-unsaturated ketones as by-products." @default.
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- W2034234653 date "2010-05-21" @default.
- W2034234653 modified "2023-09-26" @default.
- W2034234653 title "ChemInform Abstract: Lewis Acid Catalyzed Three-Component Condensation Reactions of Aldehydes, Alkoxysilanes, and Allenylsilanes: Synthesis of α-Propargyl Ethers." @default.
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- W2034234653 doi "https://doi.org/10.1002/chin.200226101" @default.
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