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- W2034237757 abstract "In view of the considerable importance of the benzyne chemistry in reactions of insertion into sigma bonds and cycloaddition reactions, which have been widely used in the synthesis of bioactive natural products 1 and in preparations of functional materials, 2 we decided to accomplish the total synthesis of (R)-(-)-aporphine (1), using as key step the [4+2] cycloaddition reaction, followed by spontaneous dehydrogenation, between methyleneisoquinoline (4) and benzyne (8), generated from 2-(trimethylsilyl)phenyl triflate (9), under mild reaction conditions. 1,3,4" @default.
- W2034237757 created "2016-06-24" @default.
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- W2034237757 date "2013-12-01" @default.
- W2034237757 modified "2023-10-04" @default.
- W2034237757 title "Study toward the synthesis of (R)-(-)-aporphine" @default.
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- W2034237757 doi "https://doi.org/10.5151/chempro-15bmos-bmos2013_2013913154342" @default.
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