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- W2034243079 abstract "Abstract The kinetics of polymerization of vinyl monomers in the presence of manganese (III) bis-(acetylacetonato)carboxylates, represented by equations, is studied. On the basis of the results a mechanism of initiation is proposed, in which an important part is played by the polar transition state. Suggestions are made about the selective action of the catalyst with respect to monomers of different structure. It is shown that the molecular weight of the polymer increases as the degree of conversion increases, as a result of participation of the double bonds of the ligand part of the initiator in propagation." @default.
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- W2034243079 date "1978-01-01" @default.
- W2034243079 modified "2023-09-25" @default.
- W2034243079 title "Initiation of polymerization of vinyl monomers by manganese (III) chelates containing unsaturated carboxylic ligands" @default.
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- W2034243079 doi "https://doi.org/10.1016/0032-3950(78)90141-7" @default.
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