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- W2034246235 endingPage "6556" @default.
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- W2034246235 abstract "Molecular mechanics calculations on the proposed cobaltacycle intermediates of the Pauson-Khand bicyclization of substituted 6-heptenynes are reported, providing the first theoretical evidence supporting the currently accepted mechanism for the Pauson-Khand reaction. In all instances, the experimentally observed configuration of the predominant bicyclo[3.3.0]oct-1-en-3-one product can be correlated with that of the most stable putative product-determining cobaltacycle, which contains a trans-fused five-membered ring Co-metallocycle." @default.
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- W2034246235 date "1995-06-01" @default.
- W2034246235 modified "2023-10-16" @default.
- W2034246235 title "A qualitative molecular mechanics approach to the stereoselectivity of intramolecular Pauson-Khand reactions" @default.
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- W2034246235 doi "https://doi.org/10.1016/0040-4020(95)00292-g" @default.
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