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- W2034250274 abstract "Ionic complexes containing μ2-hydroxo-bonded (MgPc)2OH− phthalocyanine assemblies and C60− anions: {(MgPc)2OH−}2·(C60−)2·(PMDAE+)4·(C6H5CN)4 (1); {(MgPc)2OH−}2·(C60−)2·(TMP+)4·(C6H5CN)3·(C6H4Cl2)2.5 (2) (where PMDAE+ is the cation of N,N,N′,N′,N′-pentamethyldiaminoethane and TMP+ is the N,N′N′-trimethylpiperazinium cation) have been obtained as single crystals. The ionic ground state of the complexes is justified by the EPR spectra and the spectra in the IR and NIR ranges. The C60˙− radical anions are dimerized both in 1 and 2 in the 240–220 K range. Dimerization is accompanied by the reversible transition of the complexes from paramagnetic to diamagnetic state. MgPc forms unusual (MgPc)2OH− assemblies, in which the hydroxo-anion coordinates to two MgPc molecules by a μ2-fashion. The length of the Mg–O bonds is 1.936–1.955(2) Å, the Mg–O–Mg angle is 133.37–135.27(4)° and the displacement of the Mg atoms out of the mean 24-atom phthalocyanine plane is 0.77–0.86 Å. The packing of spherical fullerene and planar phthalocyanine molecules is attained in a crystal by the insertion of fullerenes between phenylene groups of phthalocyanines. It has been shown that metal phthalocyanines in ionic complexes with C60 form MIIPc·(L−) assemblies, whereas metalloporphyrins form MIIporphyrin·(C+) assemblies." @default.
- W2034250274 created "2016-06-24" @default.
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- W2034250274 date "2012-01-01" @default.
- W2034250274 modified "2023-09-27" @default.
- W2034250274 title "Formation of μ2-hydroxo-bonded (MgPc)2OH− assemblies and (C60−)2 dimers in ionic fullerene {(MgPc)2OH−}2·(C60−)2·(cation+)4 complexes" @default.
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- W2034250274 doi "https://doi.org/10.1039/c2dt30701d" @default.
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