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- W2034250554 abstract "The absorption spectra of normal and deuterated diacetylene trapped in solid argon at 9 K were investigated in the near-ultraviolet region between 2000 and 3000 Å. The vibrational structure observed at low temperature for the band system at 2448 Å, which was previously reported by Haink and Jungen in the gas phase, and identified as a 1Δu ← X1Σg+ transition, was analyzed. A comparison between the spectra for C4H2 and C4D2 suggests some revisions in the upper-state vibrational assignments. The possibility that the upper state assumes a C2htrans configuration of 1Au symmetry is examined. The matrix spectra also appear to indicate that the absorption spectrum observed at 2576 Å in the gas phase and which has been assigned to a 1Σu− ← X1Σg+ transition may not originate in the ground state of C4H2." @default.
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- W2034250554 date "1982-07-01" @default.
- W2034250554 modified "2023-09-23" @default.
- W2034250554 title "The near-ultraviolet spectrum of diacetylene trapped in solid argon at 9 K" @default.
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- W2034250554 doi "https://doi.org/10.1016/0022-2852(82)90294-6" @default.
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