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- W2034253105 abstract "When biacetyl is photolysed in admixture with triethylborine, the replacement of ethyl by the acetyl radical competes with its decomposition. This exchange can be represented by: CH3CO +(C2H5)3B = C2H5+ CH3CO·B(C2H5)2(A)The acetyl–boron compounds were not identified in the system; the extent of reaction (A) was estimated from the number of ethyl radicals produced. When the rate of reaction (A) was related to that of the reaction CH3CO = CH3+ CO, the Arrhenius parameters found by changing the temperature from 316 to 413°K were log (A4/A5)= 1·6 ± 0·4 and (E4–E5)= 15·7 ± 0·7 kcal./mole. This points to a very low activation energy for reaction (A)." @default.
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- W2034253105 date "1968-01-01" @default.
- W2034253105 modified "2023-09-27" @default.
- W2034253105 title "Photolysis of biacetyl in the presence of triethylborine" @default.
- W2034253105 doi "https://doi.org/10.1039/j29680000264" @default.
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