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- W2034254135 abstract "The photoionization of isopropanol (i-PrOH) at 11.7 eV has been investigated in the NBS high pressure photoionization mass spectrometer over the pressure range 0.1 to approximately 200 millitorr. The major primary ion, CH3CHOH+, reacts with a total rate coefficient of 1.1 ±0.1× 10-9 cm3/mole-cule-s to yield mainly (i-PrOH)H+ and CH3(i-C3 H7)COH+. At pressures in excess of a few millitorr consecutive reactions of (i-PrOH)H+ and CH3(i-C3H7)COH+ were also detected, including the overall dehydration process (i-PrOH)H++i-PrOH→H2O+(i-C3H7)2OH+ These data are interpreted in light of a recent radiolysis study, and a thermal cationic chain mechanism for production of (I-C3H7)2O consistent with those results is proposed. The value for the proton affinity of SF6 is also discussed in some detail." @default.
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- W2034254135 title "Ion-molecule reactions in isopropanol: Implications for its radiolysis" @default.
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- W2034254135 doi "https://doi.org/10.6028/jres.076a.057" @default.
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