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• W2034257283 abstract "The chemical shifts of 4ax and 4eq substituted adamantanones are compared with those calculated with the aid of a given additivity rule. It is found that both δ carbons are shielded with respect to the substituent. In contract to the situation for the y-atoms, however, the δsyn atom is less shielded than the δanti atom. In most cases the additivity rule predicts the chemical shifts with an accuracy of approximately 1 ppm. Exceptions are carbon atoms 4 and 9 of the 4eq substituted adamantanones. In both cases the measured values are 4 to 6 ppm upfield. This can possibly be explained by an electronic interaction between the carbonyl group and the substituent." @default.
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• W2034257283 date "1975-04-01" @default.
• W2034257283 modified "2023-09-23" @default.
• W2034257283 title "Carbon-13 nuclear magnetic resonance spectra. I—Monosubstituted adamantanes and adamantanones" @default.
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• W2034257283 doi "https://doi.org/10.1002/mrc.1270070402" @default.
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