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- W2034257675 abstract "By means of the potentiodynamic method, the anodic behavior of copper is studied in perchlorate solutions in a wide range of pH and ClO 4 − ion concentrations. The activating action of ClO 4 − ions in the anodic process is associated with their weak ability to form hydrates, which facilitates their incorporation into the electrical layer and displacement of OH− ions from the surface complexes. The schemes of mechanisms proposed for the copper anodic dissolution imply the possibility of the formation of intermediate adsorption complexes with participation of ClO 4 − ions. By the technique of nonlinear regression analysis, the constants in the kinetic equations are calculated for the proposed schemes." @default.
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- W2034257675 date "2000-05-01" @default.
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- W2034257675 title "Anodic dissolution of copper in perchlorate solutions of different ionic strength" @default.
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- W2034257675 doi "https://doi.org/10.1007/bf02758392" @default.
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