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- W2034257989 abstract "Here, the synthesis of a bowl-shaped molecule is described and evidence of its reversible dimerization by means of hydrogen bonds is presented. The dimer features a flattened spherical cavity of peculiar symmetry and acts as a host for the encapsulation of guest molecules of complementary shape. Encapsulation of aromatic guests in chloroform solution and of cyclohexane in p-xylene solution was demonstrated by nuclear magnetic resonance experiments. The passage of guests into and out of the cavity is slow and occurs on a time scale of hours. The system was used to explore the effects of size, shape, and solvation on molecular recognition coupled with assembly." @default.
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- W2034257989 date "1996-01-26" @default.
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- W2034257989 title "Reversible Encapsulation of Disc-Shaped Guests by a Synthetic, Self-Assembled Host" @default.
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- W2034257989 doi "https://doi.org/10.1126/science.271.5248.487" @default.
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