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- W2034260532 abstract "γ-Ray irradiation was performed on molecular sieve 3A and 4A zeolites adsorbing various amounts of water. The enhancement of hydrogen formation was observed, and the yields of hydrogen gas due to energy transfer from the zeolites to adsorbed water were expressed as a function of p-value, a fraction of adsorbed water, in the same way as formulated in the molecular sieve 5A-water system. The results obtained in the 4A-water system showed good agreement with those in the 5A-water system, but the 3A-water system showed definite difference from the others. The present results indicate that anionic framework oxygen atoms of zeolite structure are active sites for energy transfer rather than cations contained in zeolite cavities, and that effectiveness of energy transfer process depends on the extent of mutual interaction between water molecules, cations and anionic framework oxygen atoms in cation-exchanged type A zeolites." @default.
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- W2034260532 date "1993-03-01" @default.
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- W2034260532 title "Radiolytic hydrogen gas formation from water adsorbed on type A zeolites" @default.
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- W2034260532 doi "https://doi.org/10.1016/0969-806x(93)90005-f" @default.
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