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- W2034260871 abstract "Abstract The reactivity of a [1],[1]disilamolybdenocenophane ( 1 ) towards several unsaturated substrates has been studied. Treatment of 1 with N‐heterocyclic carbene afforded an ansa ‐metallocene carbene complex. The cleavage of the P=S bond of a phosphane sulfide was observed, resulting in the incorporation of sulfur into the disila‐bridging unit and coordination of the phosphane moiety to Mo. Reactions of 1 with carbodiimide and phosphaalkyne led to side‐on coordinated products. All products were fully characterized by multinuclear NMR spectroscopy, elemental analysis, and single‐crystal X‐ray diffraction studies." @default.
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- W2034260871 date "2013-08-02" @default.
- W2034260871 modified "2023-10-10" @default.
- W2034260871 title "Reactions of a [1],[1]Disilamolybdenocenophane with Unsaturated Compounds" @default.
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- W2034260871 doi "https://doi.org/10.1002/ejic.201300766" @default.
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